Diverse reactivity of nitrones towards electron deficient acetylenes Journal Article


Author(s): Unnikrishnan, P.A.; Radhamani, S; Natarajan, R.; Prathapan, S; Rappai, J.P.
Article Title: Diverse reactivity of nitrones towards electron deficient acetylenes
Abstract: Depending on the nature of N- and C-substituents, nitrones exhibit diverse reactivity towards electron deficient acetylenes. Observed reactions include formal 1,3-dipolar cycloaddition and nucleophilic addition reactions. Possible involvement of zwitterionic intermediates and an unusual 1-aza-Cope rearrangement account for the generation of unexpected 1 : 1 adducts in the reaction of N-arylnitrones.
Journal Title: New Journal of Chemistry
Volume: 39
Publisher: The Royal Society of Chemistry and the Centre National de la Recherche Scientifique  
Date Published: 2015-05-18
Start Page: 5580
End Page: 5588
Language: English
Identifier: DOI: 10.1039/C5NJ00742A
Notes: Impact Factor 3.086